medium pressure

Plasma-activated chemical transformations promise the efficient synthesis of salient chemical products. However, the reaction pathways that lead to desirable products are often unknown, and key quantum-state-resolved information regarding the involved molecular species is lacking. Here we use quantum cascade laser dual-comb spectroscopy (QCL-DCS) to probe plasma-activated NH3 generation with rotational and vibrational state resolution, quantifying state-specific number densities via broadband spectral analysis.

A study on the scalability of discharge characteristics of a single-filament dielectric barrier discharge (DBD) to a spatially one-dimensional multi-filament arrangement driven by the same high-voltage (HV) pulses was performed for a gas mixture of 0.1 vol% O2 in N2 at 1 bar. Both arrangements feature a 1 mm gap with dielectric-covered electrodes featuring two hemispherical alumina caps for the single-filament and two parallel alumina-tubes for the multi-filament arrangement.

Modelling results obtained using an extended reaction kinetics model (RKM) suitable for the analysis of weakly ionised, non-thermal argon plasmas with gas temperatures around 300K at sub-atmospheric and atmospheric pressures are presented. Modelling was performed by means of a time- and space-dependent fluid model for two different dielectric barrier discharge configurations as well as for a micro-scaled atmospheric-pressure plasma jet setup. The results are also compared with measurements, as well as with modelling data obtained by use of a previously established 15-species RKM.

Presented data was obtained from the analysis of the impact of the electrode proximity on the streamer breakdown and development of pulsed-driven dielectric barrier discharges (DBDs) in a singlefilament arrangement in a gas mixture of 0.1 vol% O2 in N2 at 0.6 bar and 1.0 bar. The gap distance was varied from 0.5 mm to 1.5 mm, and the applied voltage was adapted correspondingly to create comparable breakdown conditions in the gap. Fast electrical measurements provided insight into discharge characteristics such as the transferred charge and consumed energy.