OES

Double-pulse laser induced breakdown spectroscopy (LIBS) measurements in water with up to 600 bar hydrostatic pressure and 150 mJ energy of each pulse were done to select a setup which promote separated spectral lines in the observed plasma emission even at elevated pressures, where line broadening until loss of the most spectral information can occur. For this a compact spectrometer und a Czerny-Turner spectrometer, both fiber-based, has been applied to investigate the dependence of the emitted radiation on different parameters and hydrostatic pressure.

Double-pulse laser induced breakdown spectroscopy (LIBS) measurements in water with up to 600 bar and 400 mJ each pulse were done to select laser parameters which promote optimized spectral line emission from plasma even at elevated pressures, where line broadening until loss of the most spectral information can occur. Optical emission spectroscopy, using a Czerny-Turner spectrometer, has been applied to investigate the dependence of the emitted radiation on laser parameters and hydrostatic pressure.

In this work we present for the first time a unified model of a low-current short-length arc between copper electrodes. The model employs one-dimensional fluid description of the plasma in argon and copper vapour at atmospheric pressure and the heat transfer in the electrodes made of copper. The solution of the particle and energy conservation of electrons and heavy particles is coupled with the solution of the Poisson equation, from which the self-consistent electric field is obtained. The operation of the non-refractory cathode is based on thermo-field emission.

An appropriate coupling of an arc plasma column in the state of local thermodynamic equilibrium to a refractory
cathode necessarily involves the non-equilibrium boundary layer between them. A model has been developed that

The dataset is the raw data (presented in numerical format) from the EPR, 1H NMR and HR-MS experiments. The respective Excel files describe the experiments to which the dataset belongs. Please refer to the original publication and ESI for more information.